Turn-key femtosecond pump-probe spectroscopy solution featuring high flexibility.

. Pump-Probe Spectrometer HARPIA.

Off-the-Shelf Pump-Probe Spectrometer

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Features

  • 350 – 1100 nm probe wavelength range
  • Ample sample space to fit a cryostat or flow system
  • Beam monitoring and self‑recalibration
  • Simple integration of any user‑preferred external spectrograph

Overview

The popular transient absorption spectrometer HARPIA has been reimagined and redesigned to meet the needs and standards of today's scientific world. The new and improved HARPIA offers a sleek and compact design and a more intuitive user experience and easy day‑to‑day maintenance. Adhering to the standards raised by the OPRHEUS line of devices, the entire spectroscopic system is now contained in a single monolithic aluminum casing that inherently ensures excellent optical stability and minimal optical path for the interacting beams. In contrast to its predecessor, the dimensions of the device are greatly reduced – the area is reduced roughly 2.6x, whereas volume is reduced nearly 4x. The new HARPIA can be easily integrated with both PHAROS / ORPHEUS and Ti:Sapph / TOPAS laser systems. Just like its precursor, it features market leading characteristics such as 10-5 resolvable signals along with other unique properties such as the ability to work at high repetition rates (up to 1 MHz) when used with PHAROS / ORPHEUS system. High repetition rate allows measuring transient absorption dynamics while exciting the samples with extremely low pulse energies (thereby avoiding exciton annihilation effects in energy transferring systems or nonlinear carrier recombination in semiconductor / nanoparticle samples).

A number of probe configurations and detection options are available starting with simple and cost effective photodiodes for single wavelength detection and ending with spectrally-resolved broadband detection combined with white light continuum probing. Data acquisition and measurement control are now integrated within the device itself and offer such improved detection capabilities as:

  • Single (sample-only) or multiple (sample and reference) integrated spectral detectors;
  • Simple integration of any user-preferred external spectrograph;
  • Beam monitoring and self-recalibration capabilities (both along the optical path of the pump/probe beams and at the sample plane) and an option for automated beam readjustment;
  • Straightforward switching between transient absorption or transient reflection measurements;
  • Capability to combine both transient absorption and Z-scan experiments on the same device;

Moreover different delay line options can be selected to cover delay windows from 2 ns (standard) to 8 ns and HARPIA may house either standard linear leadscrew (20 mm/s) or fast ball-screw (300 mm/s) optical delay stages.

A number of optomechanical peripherals are now compactly enclosed in the HARPIA casing, including:

  • An optical chopper that can either phase-lock itself to any multiple of the frequency of the laser system or operate in a free-running internally-referenced regime (standard);
  • Motorized and calibrated Berek’s polarization compensator that can automatically adjust the polarization of the pump beam (optional);
  • Motorized transversely translatable supercontinuum generator (applicable for safe and stable supercontinuum generation in materials such as CaF2 or MgF2; optional);
  • Automated sample raster scanner that translates the sample in the focal plane of the pump and probe beams, thus avoiding local sample overexposure (optional).

Moreover, the new HARPIA is designed to be compatible with any user-favored cryostat and/or peristaltic pump system (see mounting sheme). Capabilities of the new HARPIA can be further extended by introducing a third beam to the sample plane, thus allowing the user to perform multi-pulse transient absorption measurements.

A new and improved user application with experiment-guiding wizards, measurement presets, and development kit for custom applications. In addition to experiment automation software, HARPIA includes data analysis package CarpetView for inspecting the acquired data and performing global and target analysis, probe dispersion compensation, exponential fitting etc. The software package features an intuitive and user friendly interface; it is delivered with a data analysis tutorial that offers seamless transition from the raw data to publication quality graphs and model based parameter estimation. All the software runs under MS Windows and it is easy to use. Even a novice will become an analysis expert in a matter of days!

Pump-Probe Specifications
Parameter Value
Probe wavelength range supported by the optics 240 – 2600 nm
Probe wavelength range, white light supercontinuum generator, pumped by 1030 nm 350 – 750 nm, 480 – 1100 nm
Probe wavelength range, white light supercontinuum generator, pumped by 800 nm 350 – 1100 nm
Probe wavelength range of the detectors 200 nm – 1100 nm, 700 nm – 1800 nm, 1.2 μm – 2.6 μm
Spectral range of the spectral devices 180 nm – 24 μm, achievable with interchangeable gratings
Delay range 1.7 ns, 3.8 ns, 7.8 ns
Delay resolution / microstep 16.67/2.08 fs, 33.3/4.16 fs, 66.7/8.32 fs
Noise level – single wavelength 1) <10-5 (assuming 2 s averaging per point)
Noise level – multichannel detection 2) <2×10-5 (assuming 5 s averaging per spectrum)
Laser repetition rate 1 – 1000 kHz (digitizer frequency <2 kHz)
Time resolution <1.4 x the the pump or probe pulse duration (whichever is longer)
  1. 1)Test conditions: Pharos laser running at 80 kHz, pump source: Orpheus @ 480 nm; probe source 1b, spectral device 3d, detector  2a‑a. The value is standard deviation of 100 measurement points taken at the fixed delay. Not applicable for any laser system or any sample.
  2. 2)Test conditions: Pharos laser running at 64 kHz, pump source: Orpheus @ 480 nm; probe source 1b, spectral device 3d, detector 2b. The value is standard deviation of 100 measurement points taken at the fixed delay, calculated using the signal at ca. 550 nm a wavelength. Not applicable for any laser system or any sample or any spectral range covered by white light supercontinuum generator.
Dimensions
  • Photochemistry
  • Photobiology
  • Photophysics
  • Material science
  • Semiconductor physics
  • Time-resolved spectroscopy

Products List

Turn-key femtosecond pump-probe spectroscopy solution featuring high flexibility.

. Pump-Probe Spectrometer HARPIA.